The fabrication of material with an atomic scale manipulation requires the
suitable advanced substrate for epitaxial growth without the effect by the
substrate lattice structure. Hexagonal boron nitride (h-BN) can be the adva
nced substrate for atomic manipulation due to van der Waals' gap with littl
e attractive force along to c axis. We have successfully synthesized h-BN l
ayer on the co-deposited Cu/BN film by surface segregation phenomena using
helicon wave plasma enhanced radio frequency (rf) magnetron sputtering syst
em. Auger electron spectroscopy (AES) and X-ray photon spectroscopy (XPS) a
nalysis showed that the h-BN composite segregated on the surface of Cu/BN f
ilm covered over 95% of the film annealed at 900 K for 30 min. Atomic force
s microscopy (AFM) and scanning tunneling microscopy (STM) analysis showed
that attractive force on the film surface is uniformly distributed to an ex
tent of 2nN and that the h-BN surface can be a good electric insulator like
sintered h-BN plate, (C) 2001 Published by Elsevier Science B.V.