A field measurement campaign was conducted near a major road in southern Fi
nland from September 15 to October 30, 1995. The concentrations of NO, NO2
and O-3 were measured simultaneously at three locations, at three heights (
3.5, 6 and 10 m) on both sides of the road. Traffic densities and relevant
meteorological parameters were also measured on-site. We have compared meas
ured concentration data with the predictions of the road network dispersion
model CAR-FMI, used in combination with a meteorological pre-processing mo
del MPP-FMI. In comparison with corresponding results presented previously
in the literature, the agreement of measured and predicted datasets was goo
d, as measured using various statistical parameters. For all data (N = 587)
, the index of agreement (IA) was 0.83, 0.82 and 0.89 for the measurements
of NOx, NO2 and O-3 respectively. The IA is a statistical measure of the co
rrelation of the predicted and measured time series of concentrations. Howe
ver, the modelling system overpredicts NO2 concentrations with a fractional
bias FB = + 13%, and O-3 concentrations with FB = + 8%. while for NO2 conc
entrations FB = - 2%. We also analyzed the difference between model predict
ions and measured data in terms of meteorological parameters. Model perform
ance clearly deteriorated as the wind direction approached a direction para
llel to the road, and for the lowest wind speeds. The range of variability
concerning atmospheric stability, ambient temperature and the amount of sol
ar radiation was modest during the measurement campaign. As expected, no cl
ear dependencies of model performance were therefore detected in terms of t
hese parameters. The experimental dataset is available for the evaluation o
f other roadside dispersion models. (C) 2001 Elsevier Science Ltd. All righ
ts reserved.