DETERMINATION OF A POLARIZABILITY INDEX BY MEANS OF A MOLECULAR TOPOLOGY

Citation
F. Chauvin et P. Laffort, DETERMINATION OF A POLARIZABILITY INDEX BY MEANS OF A MOLECULAR TOPOLOGY, Journal de chimie physique et de physico-chimie biologique, 94(6), 1997, pp. 1216-1233
Citations number
21
Categorie Soggetti
Biology,"Chemistry Physical
Volume
94
Issue
6
Year of publication
1997
Pages
1216 - 1233
Database
ISI
SICI code
Abstract
The polarizability of the molecule is an important property to account for molecular interactions. Different polarizability indices have bee n proposed all based on the knowledge of the refraction index. This pr operty is not always easily obtained at room temperature in the liquid state. In the present study, a topological method (i.e., only based o n structure) is proposed, validated by a great number of experimental data. Also the molar volume at the boiling point has been estimated in a topological way.