Kinetic model of vinyl chloride suspension polymerization with peroxide mixture as initiator and its application

Authors
Shan, GR Weng, ZX Huang, ZM Pan, ZR
Citation
Gr. Shan et al., Kinetic model of vinyl chloride suspension polymerization with peroxide mixture as initiator and its application, CHEM J CH U, 21(12), 2000, pp. 1928-1931
Citations number
5
Categorie Soggetti
Chemistry
Journal title
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN journal
02510790 → ACNP
Volume
21
Issue
12
Year of publication
2000
Pages
1928 - 1931
Database
ISI
SICI code
0251-0790(200012)21:12<1928:KMOVCS>2.0.ZU;2-0
Abstract
On the basis of the decomposition kinetic model of peroxide mixture, a kine tic model of vinyl chloride suspension polymerization with peroxide mixture as initiator was derived and can be used to predict the kinetics of vinyl chloride polymerization in good agreement with the experimental data. The i nitiator efficiency of TxEHP, Tx99, Tx23 and Tx36 at 51 or 57 degreesC was obtained from the kinetic data of VC polymerization initiated by single ini tiator.