From 6-t-butylfulvene to highly functionalized five-membered rings

Authors
Baumgartner, J Weber, H
Citation
J. Baumgartner et H. Weber, From 6-t-butylfulvene to highly functionalized five-membered rings, CHIRALITY, 13(3), 2001, pp. 159-163
Citations number
28
Categorie Soggetti
Chemistry & Analysis
Journal title
CHIRALITY
ISSN journal
08990042 → ACNP
Volume
13
Issue
3
Year of publication
2001
Pages
159 - 163
Database
ISI
SICI code
0899-0042(2001)13:3<159:F6THFF>2.0.ZU;2-1
Abstract
6-t-Butylfulvene was used as the starting material for asymmetric dihydroxy lation. The obtained protected diol (2) was used for several stereoselectiv e functionalizations such as epoxidations, hydroboration, and aminohydroxyl ation. However, these fulvene derivatives proved to be rather unreactive an d gave no conversion under, e.g., palladium (0), catalyses or hydroboration conditions. Chirality 13.159-163, 2001. (C) 2001 Wiley-Liss, Inc.