Xanthate mediated generation of the benzotriazol-1-ylmethyl radical and its subsequent addition to a variety of olefins

Citation
Ar. Katritzky et al., Xanthate mediated generation of the benzotriazol-1-ylmethyl radical and its subsequent addition to a variety of olefins, HETEROCYCLE, 54(1), 2001, pp. 301-308
Citations number
13
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
HETEROCYCLES
ISSN journal
03855414 → ACNP
Volume
54
Issue
1
Year of publication
2001
Pages
301 - 308
Database
ISI
SICI code
0385-5414(20010101)54:1<301:XMGOTB>2.0.ZU;2-J
Abstract
The first generation of the benzotriazol-1-ylmethyl radical (3) is reported from S-(1H-1,2,3-benzotriazol-1-ylmethyl)-O-ethylcarbonodithioate (1). Sub sequent additions of radical (3) to a variety of olefins are demonstrated.