One- and two-photon excitation (OPE and TPE) spectra of single 1,8-dip
henyloctatetraene molecules in n-tetradecane (transition at 444 nm) we
re recorded at cryogenic temperature. The high-power infrared light us
ed for TPE changed the conditions in the sample so that the number of
single molecule lines observed in OPE spectra was approximately twice
the number in TPE spectra or OPE spectra with added infrared illuminat
ion. Single molecules detectable under OPE and TPE, only under OPE, an
d only under TPE were observed.