A systematic study of the near-band-edge photoluminescence of epitaxia
lly grown GaN as a function of excitation density has been carried out
. While at low densities free and bound-exciton emission lines govern
the spectrum, new luminescence bands are detected at densities above 1
MW/cm(2). Gain measurements and temperature-dependent investigations
indicate that nonlinear processes like biexciton annihilation, exciton
-exciton-scattering and stimulated A-LO-emission are dominant at low t
emperatures, while exciton-free-carrier scattering occurs at temperatu
res above 200 K.