LUMINESCENT PROPERTIES AND PHOTOGENERATION OF CHARGE-CARRIERS IN PORPHYRIN DIMERS AND MOLECULAR PHOTO-DIODES

Authors
SCHAAFSMA TJ SAVENIJE TJ KOEHORST RBM VERGELDT FJ WIENKE J
Citation
Tj. Schaafsma et al., LUMINESCENT PROPERTIES AND PHOTOGENERATION OF CHARGE-CARRIERS IN PORPHYRIN DIMERS AND MOLECULAR PHOTO-DIODES, Journal of luminescence, 72-4, 1997, pp. 81-82
Citations number
6
Categorie Soggetti
Optics
Journal title
Journal of luminescence → ACNP
ISSN journal
00222313
Volume
72-4
Year of publication
1997
Pages
81 - 82
Database
ISI
SICI code
0022-2313(1997)72-4:<81:LPAPOC>2.0.ZU;2-P
Abstract
Charge carrier photogeneration in solid porphyrin films was investigat ed using optical and photocurrent action spectroscopy. In electropolym erized DA porphyrin films on ITO, acting as photo diodes, unidirection al charge separation occurs within interfacial heterodimers if E-D,E-A (S-1)-E-CT in solution is sufficiently large. In covalent porphyrin di mers on TiO2, one of the porphyrins can act as an antenna for the phot oelectrically active component.