The state-of-the-art of our fundamental understanding of a large numbe
r of well-known luminescent ions used since long in phosphors is revie
wed. These ions are WO42-, VO43-, Sb3+, Bi2+, Bi3+, Cu+, and Ce3+. The
conclusion is that quantitative understanding is lacking and that in
several cases even a qualitative explanation of the luminescence obser
ved is not available.