F. Auzel et al., DETERMINATION OF THE QUANTUM EFFICIENCY OF ER3- INDIRECT AND DIRECT-METHODS( IN GLASSES ), Journal of luminescence, 72-4, 1997, pp. 152-154
We compare quantum efficiency for erbium doped silica and fluoride gla
sses as determined by the ratio of measured to calculated radiative li
fetimes, with results directly measured by photoacoustics. Comparison
shows that results are similar for fluoride glasses, whereas discrepan
cies are found for silica glasses. Such difference is traced back to t
he role of ligand field strength at the erbium ion site in the applica
tion of Einstein relation linking spontaneous and stimulated emission.