Bis(3,5-dimethylpyrazole-1-carbodithioato) nickel(II) and its transformation to a dinuclear complex: Crystal structure of [Ni-2(mu-3,5-Me(2)Pz)(2)(L-1)(2)] (L-1=3,5-dimethylpyrazole-1-carbodithioate)

Authors
Mukhopadhyay, S Mukhopadhyay, U Mak, TCW Ray, D
Citation
S. Mukhopadhyay et al., Bis(3,5-dimethylpyrazole-1-carbodithioato) nickel(II) and its transformation to a dinuclear complex: Crystal structure of [Ni-2(mu-3,5-Me(2)Pz)(2)(L-1)(2)] (L-1=3,5-dimethylpyrazole-1-carbodithioate), INORG CHEM, 40(5), 2001, pp. 1057
Citations number
33
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
40
Issue
5
Year of publication
2001
Database
ISI
SICI code
0020-1669(20010226)40:5<1057:BNAIT>2.0.ZU;2-I
Abstract
The reaction of NiCl2. 6H(2)O with potentially bidentate N,S donor pyrazole -1-carbodithioate ligands produces four-coordinated diamagnetic (NiN2S2)-N- II complexes quantitatively. In solution Ni(L-1)(2) (L-1 = 3,5-dimethylpyra zole-1-carbodithioate) transforms to dimeric bis(3,5-dimethylpyrazole-1-car bodithioato) bis(mu -3,5-dimethylpyrazolato)dinickel(II), [Ni-2(mu -3,5-Me( 2)Pz)(2)(L-1)(2)] (1).