Structure variation due to ligand flexibility: Syntheses and structures ofthe copper(II) complexes [Cu(APPy)] and [Cu-2(AEPy)(2)] where APPyH(2) = bis[3-(2-pyridinecarboxamido)propyl]methylamine and AEPyH(2) = bis[3-(2-pyridinecarboxamido)ethyl]methylamine

Authors
Rowland, JM Thornton, ML Olmstead, MH Mascharak, PK
Citation
Jm. Rowland et al., Structure variation due to ligand flexibility: Syntheses and structures ofthe copper(II) complexes [Cu(APPy)] and [Cu-2(AEPy)(2)] where APPyH(2) = bis[3-(2-pyridinecarboxamido)propyl]methylamine and AEPyH(2) = bis[3-(2-pyridinecarboxamido)ethyl]methylamine, INORG CHEM, 40(5), 2001, pp. 1069
Citations number
39
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
40
Issue
5
Year of publication
2001
Database
ISI
SICI code
0020-1669(20010226)40:5<1069:SVDTLF>2.0.ZU;2-I
Abstract
Two new pentacoordinate ligands containing two pyridine 2-carboxamide units connected by -(CH2)(n)-N(Me)-(CH2)(n)- links have been synthesized. The li gand with n = 3 affords a monomeric Cu(II) complex, while the one with n = 2 gives rise to a ligand-shared dimer.