CHEMICALLY TUNED ZERO-FIELD SPLITTINGS AND SPIN-LATTICE RELAXATION - INVESTIGATION BY TIME-RESOLVED EMISSION

Authors
YERSIN H STRASSER J
Citation
H. Yersin et J. Strasser, CHEMICALLY TUNED ZERO-FIELD SPLITTINGS AND SPIN-LATTICE RELAXATION - INVESTIGATION BY TIME-RESOLVED EMISSION, Journal of luminescence, 72-4, 1997, pp. 462-463
Citations number
11
Categorie Soggetti
Optics
Journal title
Journal of luminescence → ACNP
ISSN journal
00222313
Volume
72-4
Year of publication
1997
Pages
462 - 463
Database
ISI
SICI code
0022-2313(1997)72-4:<462:CTZSAS>2.0.ZU;2-0
Abstract
For the compounds studied, zero-field splittings (zfs) of the lowest t riplets lie between about 0.1 and 200 cm(-1). This energy determines s pin-lattice relaxation (sir) rates and thus time developments of the e mission. It is possible to shift these relaxation times into pre-defin ed time regions. The importance of these properties is demonstrated fo r the representative [Ru(bpy)(3)](2+).