Steady-state fluorescence spectra and time correlated single-photon co
unting measurements were performed on samples of poly(vinyl alcohol),
poly(vinyl acetate) and their blends in different proportions (9/1, 1/
1 and 1/9) containing fluorescein and/or anthracene probes. The interf
ace thickness, the surface to volume ratio of microdomains and the het
erogeneity of the samples were determined from those measurements.