The photoluminescence (PL) spectra of MOCVD-grown GaAs samples have be
en measured at 10 K, and for the most representative sample: PL spectr
a were recorded from 10 to 150 K. Besides of the well-established tran
sitions, a hitherto unreported peak was seen at 1.454 eV. The identifi
cation of a line at 1.408 eV is also discussed.