CHARACTERIZATION OF INTRALIGAND CHARGE-TRANSFER TRANSITIONS IN PD(QOL)(2), PT(QOL)(2) AND PT(QTL)(2) INVESTIGATED BY SHPOLSKII SPECTROSCOPY

Authors
DONGES D NAGLE JK YERSIN H
Citation
D. Donges et al., CHARACTERIZATION OF INTRALIGAND CHARGE-TRANSFER TRANSITIONS IN PD(QOL)(2), PT(QOL)(2) AND PT(QTL)(2) INVESTIGATED BY SHPOLSKII SPECTROSCOPY, Journal of luminescence, 72-4, 1997, pp. 658-659
Citations number
7
Categorie Soggetti
Optics
Journal title
Journal of luminescence → ACNP
ISSN journal
00222313
Volume
72-4
Year of publication
1997
Pages
658 - 659
Database
ISI
SICI code
0022-2313(1997)72-4:<658:COICTI>2.0.ZU;2-C
Abstract
Pd(qol)(2), Pt(qol)(2) and Pt(qtl)(2) are investigated in n-octane Shp ol'skii matrices at T = 1.2 K. For the first time, it is possible to o btain highly resolved phosphorescence and triplet as well as singlet e xcitation spectra. The corresponding excited states are assigned to in traligand charge transfer (ILCT) transitions. Their characteristic ele ctronic and vibrational properties are studied in detail.