Mid-band-gap emissions in GaN epilayers grown on 6H-SiC and sapphire a
re studied by time-resolved spectroscopy (TRS). The yellow luminescenc
e peaking at ca. 1.2 eV at low-temperature shifts to higher energies w
ith increasing temperature. The presence of emission with the same cha
racteristics in samples grown on different substrates and by different
processes indicates that the defects responsible for the emission are
of intrinsic nature but dependent on the cubic or hexagonal habit of
the crystals. TRS are compared with cathodoluminescence (CL) in a scan
ning electron microscope (SEM) and optically detected magnetic resonan
ce (ODMR) data.