The photoluminescence spectrum of PbWO4 is composed of blue and green
bands, previously attributed to the regular WO4 group and to the defec
t-related WO3 group, respectively, Untill now only green emission was
observed in the thermostimulated luminescence (TSL) above 77 K. Invest
igation of the TSL spectra starting from 20 K indicates that the blue
band, being definitely present at least in the 28 K TSL peak, is also
due to recombination emission at defect sites.