Method for determination of methyl tert-butyl ether in gasoline by gas chromatography

A simple method for the determination of methyl tert-butyl ether (MTBE) in gasoline has been developed. The separation of MTBE from other analytes was controlled by the use of gas chromatography-mass spectrometry in the full scan mode using the characteristic primary, secondary and tertiary ions m/z 73, 57 and 43. The sample mass spectrum did not show any superimposition o f other analytes. The separation from the common gasoline component 2-methy lpentane was sufficient for reliable quantitation. An application of the de veloped conditions using gas chromatography with flame ionization detection was performed by the analysis of regular, euro super, super premium unlead ed and 'Optimax' gasoline from petrol stations in the area of Frankfurt/Mai n, Germany. Regular unleaded gasoline shows an average MTBE content of 0.4% (w/w), whereas the MTBE content in euro super gasoline varies between 0.4 and 4.2% (w/w). The blending of MTBE to super premium has increased from 8. 2% (w/w) in 1998 to 9.8% (w/w) on average in 1999. The recently introduced gasoline 'Optimax' shows an average MTBE content of 11.9% (w/w). The presen ted method might also be used for the analysis of other ethers, such as eth yl tert-butyl ether, which requires the use of another internal standard. ( C) 2001 Elsevier Science B.V. All rights reserved.