The development of a water-based pretreatment system containing chestnut ta
nnin and phosphoric acid and the assessment of its anticorrosive properties
through different conventional tests are discussed in this work. Treated s
teel panels coated with different paint systems were subjected to standardi
zed (salt spray, humidity chamber, adhesion, and flexibility) and electroch
emical (corrosion potential, EIS) tests. electrochemical tests were perform
ed by employing only panels coated with the wash primer to determine its pr
otective effect. The binder employed in this research was prepared in the l
aboratory by emulsion polymerization of acrylic monomers.
It was found that the tested formulation protected steel against corrosion
by forming ferric tannate, which prevented oxide formation. After performin
g the salt spray tests, it was observed that no oxide spots developed on th
e scratch mark, although some blisters were detected. The good stability of
the binder in low pH media (pH: 2.0-2.5) and the binder/substrate interact
ion are decisive factors in the performance of this aqueous pretreatment sy
stem.