The complex effects of the sensitisation of laser crystals on the spec
tral and temporal behaviour of the activator emission is discussed. It
is thus shown that the mutual crystal-field perturbations produced by
the sensitizer S and activator A ions transforms the systems formed b
y these ions into inhomogeneous systems composed of homogeneous subsys
tems, which are further individualised by specific manifestation of th
e S-A energy transfer processes. A suitable rate equation modelling fo
r each of the S-A subsystems which takes into account the energy trans
fer between the subsystems enables a correct description of the emissi
on properties in various laser crystals under selective or non-selecti
ve pump.