C. Pearson et al., Metal ion sensing using ultrathin organic films prepared by the layer-by-layer adsorption technique, J PHYS D, 34(3), 2001, pp. 285-291
Bilayer films of poly(ethyleneimine) and poly(ethylene-co-maleic acid) have
been prepared using the layer-by-layer assembly technique. These films hav
e been characterized using surface plasmon resonance (SPR). Exposure to aqu
eous solutions of metal acetate (metal = copper, nickel) resulted in a shif
t in the position of the SPR curve. This shift could be monitored by observ
ing the intensity of the reflected laser beam at fixed angle and concentrat
ions of copper acetate down to at least 10(-6) M could be detected.