Nm. Nesterenko et al., Raman scattering in the vicinity of the ferroelastic phase transition to the monoclinic phase in KSc(MoO4)(2), LOW TEMP PH, 27(2), 2001, pp. 148-152
The low-energy lattice modes are investigated above and below the temperatu
re of the phase transition from the trigonal to the monoclinic phase in KSc
(MoO4)(2) by the Raman scattering method. The Raman spectra exhibit anomali
es at temperatures above the phase transition to the monoclinic phase (T si
milar to 260 K) in the region of external oscillations of the tetrahedral a
nion. Anomalous behavior of the damping A(g) of the soft mode is observed i
n the temperature region 240-260 K. A model of the phase transition is disc
ussed. (C) 2001 American Institute of Physics.