The study reports the discovery of a new structure and spacing versus angle
relation for a prevalent type of small-angle grain boundary in YBa2Cu3O7-d
elta (YBCO)-coated conductor films. Small-angle [001] tilt grain boundaries
with (110) planes exhibit partial grain boundary dislocations (GBDs) separ
ated by stacking faults. The dissociated grain boundary structures have twi
ce the number of GBDs and shorter interdislocation core channel widths than
Frank's geometrical rule predicts. This will require a significant alterat
ion of models of supercurrent flow through arrays of small-angle grain boun
daries in YBCO coated conductors. A thorough analysis of the stacking fault
energy has been conducted based on the basis of anisotropic elasticity.