The pressure behavior of the phonon modes of tetragonal two-dimensional pol
ymeric C-60 has been studied at pressure up to 27.5 GPa and room temperatur
e by means of Raman spectroscopy. Gradual transformation of the material to
a new phase was observed in the pressure region 18.0-22.0 GPa. The Raman s
pectrum characteristics of the high-pressure phase provide a strong indicat
ion that the fullerene molecular cage is retained and the material map be r
elated to a three-dimensionally polymerized C-60. The new phase remains sta
ble upon pressure decrease down to 9 GPa. Further release of pressure leads
to its transformation to a highly disordered structure whose broad feature
s in the Raman spectrum resemble those of amorphous carbon.