An approach is suggested for the investigation of pressure-induced semicond
uctor-metal phase transitions in a wide group of materials based on both th
e model of p-bonds and Peierls distortion of lattice and the experimental r
esults of thermoelectrical and magnetoresistance measurements at high press
ures P up to 30 GPa. Cubic sphalerite (HgSeS and HgTeS), sphalerite with 11
3 vacancy in cation sites (In2Tc3 acid Ga2Te3), trigonal chain semiconducto
rs (Te and Se), It, and chalcogenides (Zn, Cd, Sm, Eu) an analyzed in the f
rame of this approach.