The transport of charged species in collisional currentless plasmas is trad
itionally thought of as a diffusion-like process. In this paper, it is demo
nstrated that, in contrast to two-component plasma, containing electrons an
d positive ions, the transport of additional ions in multispecies plasmas i
s not governed by diffusion, rather described by nonlinear convection. As a
particular example, plasmas with the presence of negative ions have been s
tudied. The velocity of a small perturbation of negative ions was found ana
lytically and validated by numerical simulation. As a result of nonlinear c
onvection, initially smooth ion density profiles break and form strongly in
homogeneous shock-like fronts. These fronts are different from collisionles
s shocks and shocks in fully ionized plasma. The structure of the fronts ha
s been found analytically and numerically. (C) 2001 American Institute of P
hysics.