A new classification of chemical structural units (csu), based on their ele
mental chemical transformations, is presented. It origins from a new unifor
m numerical definitions of acids, bases, oxidators and reductors and a new
numerical approach to the periodic chart of elements. According to these as
sumptions csu and their combinations are distributed in a multi-dimensional
classification space. Much attention has been paid to prove experimentally
that the virtual classification steps present the real steps of chemical r
eactions of csu. Thermal decomposition stages as well as syntheses of salts
in solid state were investigated. Applications of classification presented
in research and didactics have been discussed.