Structure development and properties of PET fibre filled PP composites

Citation
C. Saujanya et S. Radhakrishnan, Structure development and properties of PET fibre filled PP composites, POLYMER, 42(10), 2001, pp. 4537-4548
Citations number
37
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
POLYMER
ISSN journal
00323861 → ACNP
Volume
42
Issue
10
Year of publication
2001
Pages
4537 - 4548
Database
ISI
SICI code
0032-3861(200105)42:10<4537:SDAPOP>2.0.ZU;2-W
Abstract
The structure development and mechanical properties of polypropylene CPP) c omposite containing polyethylene terephthalate (PET) fibres were studied bo th in the presence and absence of a compatibilizer such as maleic anhydride (MA). The structural and morphological studies were carried out by WAXD, o ptical microscopy and SEM techniques. In the absence of MA, the PET fibres in PP showed transcrystalline morphology and thus proved to be a strong nuc leating agent for PP spherulites. On the other hand, in the presence of MA, no transcrystalline growth of PP was observed on the surface of PET fibres . The fibre to matrix bonding was better in presence of MA than without it, as was revealed by SEM of fractured surfaces. The mechanical properties vi z. impact strength and tensile modulus showed enhancement for these composi tes as compared to pure PP. However, pronounced increase in the properties was seen for PET fibres filled PP composite without MA. The above findings could be understood in terms of high aspect ratio for PET fibres, transcrys talline morphology, good fibre-matrix adhesion and nucleating ability of PE T fibres in PP matrix. (C) 2001 Elsevier Science Ltd. All rights reserved.