A. Toda et Y. Saruyama, A modeling of the irreversible melting kinetics of polymer crystals responding to temperature modulation with retardation of melting rate coefficient, POLYMER, 42(10), 2001, pp. 4727-4730
An extension of the modeling proposed previously has been examined for the
irreversible melting kinetics of polymer crystals on heating with response
to temperature modulation. The previous modeling has been successful in the
explanation of the frequency dependence of the apparent heat capacity obta
ined with temperature modulated DSC in the melting region of poly(ethylene
terephthalate), polyethylene and poly(caprolactam). In the present work thi
s modeling was extended to explain an unusual behavior reported by Schawe e
t al. for poly(epsilon -caprolactone) and syndiotactic polypropylene, in wh
ich the latent heat gave a substractive effect to the real part of the appa
rent heat capacity. A retardation of the melting rate coefficient in respon
se to temperature change has been considered. The retardation implies an ac
tivation process in the melting kinetics of polymer crystals. (C) 2001 Else
vier Science Ltd. All rights reserved.