Ia. Farhat et al., Water redistribution during the recrystallisation of amylopectin in amylopectin/gelatin blends, POLYMER, 42(10), 2001, pp. 4763-4766
The DMTA thermogram of 50:50:32 gelatin/amylopectin/water extrudates showed
two main transitions: 24 and 52 degreesC associated with the glass transit
ion temperatures (T(g)s) Of gelatin and amylopectin, respectively. After st
orage (15 days, 60 degreesC), amylopectin recrystallised to the A-polymorph
. This was paralleled by a decrease of the T-g of gelatin to 1.5 degreesC,
which was explained in terms of water redistribution during the formation o
f amylopectin crystallites. A full analysis of water partitioning in the sy
stem is reported. (C) 2001 Elsevier Science Ltd. All rights reserved.