Electrosynthesis and oxidation of new oligoazomethines containing N-ethylcarbazole groups

Citation
C. Chevrot et T. Henri, Electrosynthesis and oxidation of new oligoazomethines containing N-ethylcarbazole groups, SYNTH METAL, 118(1-3), 2001, pp. 157-166
Citations number
26
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
118
Issue
1-3
Year of publication
2001
Pages
157 - 166
Database
ISI
SICI code
0379-6779(20010301)118:1-3<157:EAOONO>2.0.ZU;2-O
Abstract
Oligoazomethines containing the N-ethylcarbazole group have been synthesize d by dehalogenative polycondensation of dibromides of N-ethylcarbazole-azom ethine as monomer in the presence of electrogenerated zerovalent nickel act ing as a catalyst. Chemical oxidation of these new compounds by FeCl3 was s tudied by optical spectroscopy and electrochemical oxidation by cyclic volt ammetry. (C) 2001 Elsevier Science B.V. All rights reserved.