Asymmetric addition of diethylzinc to N-(diphenylphosphinoyl) imines

Authors
Pinho, P Andersson, PG
Citation
P. Pinho et Pg. Andersson, Asymmetric addition of diethylzinc to N-(diphenylphosphinoyl) imines, TETRAHEDRON, 57(8), 2001, pp. 1615-1618
Citations number
25
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
57
Issue
8
Year of publication
2001
Pages
1615 - 1618
Database
ISI
SICI code
0040-4020(20010218)57:8<1615:AAODTN>2.0.ZU;2-G
Abstract
The addition of dialkylzinc reagents to N-(diphenylphosphinoyl) imines is a convenient method for the preparation of optically enriched amines. Herein we present our most recent results on this reaction, including solvent eff ects on the enantioselectivity and the extension of this method to a variet y of N-(diphenylphosphinoyl) imines. (C) 2001 Elsevier Science Ltd. All rig hts reserved.