An FT-IR study of the adsorption and oxidation of N-containing compounds over Fe2O3-TiO2SCR catalysts

Authors
Larrubia, MA Ramis, C Busca, G
Citation
Ma. Larrubia et al., An FT-IR study of the adsorption and oxidation of N-containing compounds over Fe2O3-TiO2SCR catalysts, APP CATAL B, 30(1-2), 2001, pp. 101-110
Citations number
34
Categorie Soggetti
Physical Chemistry/Chemical Physics","Environmental Engineering & Energy
Journal title
APPLIED CATALYSIS B-ENVIRONMENTAL
ISSN journal
09263373 → ACNP
Volume
30
Issue
1-2
Year of publication
2001
Pages
101 - 110
Database
ISI
SICI code
0926-3373(20010226)30:1-2<101:AFSOTA>2.0.ZU;2-M
Abstract
The interaction of NO, ammonia (NH3), hydrazine (N2H4), hydroxylamine (NH2O H), urea (H2N-CO-NH2), acetamide (CH3-CO-NH2) and acetonitrile (CH3CN) on F e2O3-TiO2 model catalysts was studied. The data support the idea that hydra zine can be intermediate in the oxidation of ammonia to nitrogen, while hyd roxylamine-type species, formed at higher temperature, can be intermediate in the oxidation of ammonia to NO. Bronsted acid sites do not appear to be involved in this chemistry. (C) 2001 Elsevier Science B.V. All rights reser ved.