Synthesis and properties of a stable, cationic, rhodium Lewis-acid catalyst for hydrosilation, Mukaiyama aldol and cyclopropanation reactions

Authors
Dias, EL Brookhart, M White, PS
Citation
El. Dias et al., Synthesis and properties of a stable, cationic, rhodium Lewis-acid catalyst for hydrosilation, Mukaiyama aldol and cyclopropanation reactions, CHEM COMMUN, (5), 2001, pp. 423-424
Citations number
16
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
5
Year of publication
2001
Pages
423 - 424
Database
ISI
SICI code
1359-7345(2001):5<423:SAPOAS>2.0.ZU;2-6
Abstract
The remarkably stable cationic, three-coordinate, 14-electron rhodium compl ex 1 has been synthesized, isolated and used as a catalyst for hydrosilatio n, Mukaiyama aldol and cyclopropanation reactions.