Solvothermal synthesis of [Ni(C4H13N3)(2)](2)Sb4S8: the first compound with a cyclic [Sb4S8](4-) anion

Authors
Bensch, W Nather, C Stahler, R
Citation
W. Bensch et al., Solvothermal synthesis of [Ni(C4H13N3)(2)](2)Sb4S8: the first compound with a cyclic [Sb4S8](4-) anion, CHEM COMMUN, (5), 2001, pp. 477-478
Citations number
28
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
5
Year of publication
2001
Pages
477 - 478
Database
ISI
SICI code
1359-7345(2001):5<477:SSO[TF>2.0.ZU;2-Q
Abstract
Under mild hydrothermal conditions the novel thioantimonate(iii) [Ni(C4H13N 3)(2)](2)Sb4S8 was synthesised using elemental nickel, antimony and sulfur; the structure is composed of cyclic isolated [Sb4S8](4-) anions and [Ni(C4 H13N3)(2)](2+) cations.