In-situ electrochemical synthesis of the metalloporphyrins with the help of the voltammetry of immobilized microparticles

Authors
Zhuang, QK Scholz, F
Citation
Qk. Zhuang et F. Scholz, In-situ electrochemical synthesis of the metalloporphyrins with the help of the voltammetry of immobilized microparticles, CHEM J CH U, 22(2), 2001, pp. 171-174
Citations number
15
Categorie Soggetti
Chemistry
Journal title
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN journal
02510790 → ACNP
Volume
22
Issue
2
Year of publication
2001
Pages
171 - 174
Database
ISI
SICI code
0251-0790(200102)22:2<171:IESOTM>2.0.ZU;2-E
Abstract
Upon cyclic electrochemical polarization, traces of 5, 10, 15, 20-tetraphen yl-21H, 23H-porphyrin(H2TPP), which have been mechanically transferred to t he surface of a paraffin-impregnated graphite electrode, can incorporate co pper, iron or cobalt ions from aqueous solution into the porphyrin ring to form CuTPP, FeTPPCl and CoTPPCl, The binding of metal ions by H2TPP can be studied by voltammetry of immobilized microparticles. The mechanism of form ation and reaction of the metalloporphyrins and their electrocatalytic prop erties were elucidated.