A study of asymmetric Baeyer-Villiger reaction of 2-phenylcyclohexanone catalyzed by chiral Salen-Cu(II) and oxazolnie-Cu(II) complexes

Authors
Peng, YG Feng, XM Wang, B Li, Z Yang, GS Jiang, YZ
Citation
Yg. Peng et al., A study of asymmetric Baeyer-Villiger reaction of 2-phenylcyclohexanone catalyzed by chiral Salen-Cu(II) and oxazolnie-Cu(II) complexes, CHEM J CH U, 22(2), 2001, pp. 223-227
Citations number
12
Categorie Soggetti
Chemistry
Journal title
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN journal
02510790 → ACNP
Volume
22
Issue
2
Year of publication
2001
Pages
223 - 227
Database
ISI
SICI code
0251-0790(200102)22:2<223:ASOABR>2.0.ZU;2-4
Abstract
In this paper, we have studied the asymmetric Baeyer-Villiger reaction of 2 -phenylcyclohexanone catalyzed by Cu( II ) complexes which derived from a s eries of chiral Salen and oxazoline ligands, as well as designed and synthe sized the new chiral ligands III, IV, V, And the configuration of complex V -Cu( II ) was determined by X-ray analysis. We also investigated the influ ence of co-oxidant, solvent, etc. on the reactivity and selectivity.