Syntheses and crystal structures of novel di- and trinuclear rhodium complexes bridged by pyrazine

Authors
Yu, XY Maekawa, M Kondo, M Kitagawa, S Jin, GX
Citation
Xy. Yu et al., Syntheses and crystal structures of novel di- and trinuclear rhodium complexes bridged by pyrazine, CHEM LETT, (2), 2001, pp. 168-169
Citations number
13
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
2
Year of publication
2001
Pages
168 - 169
Database
ISI
SICI code
0366-7022(20010205):2<168:SACSON>2.0.ZU;2-Y
Abstract
Never di- and trinuclear Rh complexes, [Rh-2(PPh3)(4)(H)(4)(Me2CO)(2)(mu -p yz)](ClO4)(2). EtOH and [Rh-3(PPh3),(mu -pyz)(3)](ClO4)(3). EtOH were selec tively isolated from the reaction of [Rh(PPh3)(2)(H)(2)(Me2Co)(EtOH)]ClO4 w ith pyrazine (pyz) in Me2CO and THF, respectively. Their structures were cr ystallographically characterized.