The volumetric mass transfer coefficient, K(L)a, was determined by dynamic
method in a surface aerated pilot scale squared vessel up to 0.531m(3) equi
pped with Simcar type impeller. Through surface aeration, the oxygen transf
er characteristics were investigated with the variations of operating varia
bles such as stirring speed, impeller diameter, liquid height and power inp
ut per liquid volume (Po/V). It was seen ham the results of different oxyge
n concentration absorption that the dynamic method might lead to errors in
K(L)a when air was used for absorption. To provide reliable K(L)a values me
asured by dynamic. the K(L)a data using pure oxygen were used and confirmed
with feeding steady-state method (FSM). As expected, K(L)a depends on Po/V
, impeller size and liquid height. However, for Simcar type impeller, the K
(L)a shows linear dependency on Po/V in contrast to majority of correlation
s reported in the literature which shows K(L)a a (po/V)(0.65) for disk type
impeller. Moreover, it was interesting to find that the bubble behaviors i
nside the vessel computed by computational fluid dynamics (CFD) could expla
in qualitatively the K(L)a changes with operating variables. For the purpos
e of scale-up procedures, the empirical correlations for predicting K(L)a w
ere developed within +/-2% accuracy.