Structural investigations of oligomeric axially bridged ruthenium phthalocyanines by EXAFS spectroscopy

Authors
Weber, A Ertel, TS Reinohl, U Feth, M Bertagnolli, H Leuze, M Hanack, M
Citation
A. Weber et al., Structural investigations of oligomeric axially bridged ruthenium phthalocyanines by EXAFS spectroscopy, EUR J INORG, (3), 2001, pp. 679-684
Citations number
36
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
14341948 → ACNP
Issue
3
Year of publication
2001
Pages
679 - 684
Database
ISI
SICI code
1434-1948(200103):3<679:SIOOAB>2.0.ZU;2-R
Abstract
To obtain more information about the structure of phthalocy-aninatorutheniu m compounds an EXAFS investigation was carried out on amorphous bisaxially bridged phthaloxyanina-toruthenium(II) oligomers, [PcRu(tz)](n) (1), [PcRu( pyz)](n) (2) and [PcRu(dib)](n) (3). Detailed structural models for the thr ee compounds were deduced from the determined atomic distances around the m etal center. A bisaxial structure of the ligands could be proven for all co mpounds and additionally, the structure parameters could be determined.