The strain compensation effects on the valence subbands and on the optical
properties of CaInAs/AlCaInAs quantum well structures are theoretically stu
died for the first time. In the case of compressive-strained quantum wells,
where the top valence subbands are always formed with heavy hole (HH) subb
ands, the compensatingly tensile-strained barriers shift the first light ho
le (LH) subbands upward increasing the valence band mixing between them, an
d significantly reducing the transverse electric (TE) gain. In contrast, in
the tensile-strained quantum wells whose top valence subband is formed wit
h LH subband, the compensatingly compressive-strained barriers shift the to
p LH subband downward and on some occasions the top LH subband is replaced
with the first HH one. The increase of the TE gain is relatively small due
to the strong valence band mixing. The strain of the barrier layers is foun
d to play an important role in the valence subband structures and optical p
roperties.