Five phenolic constituents have been identified in Yucca schidigera bark, a
nd their structures were established by spectral (FABMS and NMR) experiment
s. These included two known stilbenes, trans-3,4',5-trihydroxystilbene (res
veratrol) and trans-3,3',5,5'-tetrahydroxy-4'-methoxystilbene, as well as t
hree novel compounds, yuccaols A, B, and C, with spiro-structures rarely oc
curring in the plant kingdom. It is suggested that yuccaols A-C are biosynt
hethized via attachment of a stilbenic derivative to the carbocationic inte
rmediate of the oxidative flavanone-flavonol conversion.