The effect of 4 '-substituents on the kinetics of ligand substitution in 2,2 ': 6 ',2 ''-terpyridine platinum(II) complexes

Authors
Carr, CA Richards, JM Ross, SA Lowe, G
Citation
Ca. Carr et al., The effect of 4 '-substituents on the kinetics of ligand substitution in 2,2 ': 6 ',2 ''-terpyridine platinum(II) complexes, J CHEM R-S, (12), 2000, pp. 566-568
Citations number
18
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF CHEMICAL RESEARCH-S
ISSN journal
03082342 → ACNP
Issue
12
Year of publication
2000
Pages
566 - 568
Database
ISI
SICI code
0308-2342(200012):12<566:TEO4'O>2.0.ZU;2-V
Abstract
The rates of hydrolysis of five (4'-substituted-2,2':6',2 " -terpyridine) p latinum(II) (n-propylamine) complexes exhibit a high sensitivity to the ele ctronic properties of the terpyridine ligand; analysis using the Hammett re lationship gives a rho value of +2.34.