Pyrolysis-capillary gas chromatography-mass spectrometry for the determination of polyvinyl chloride traces in solid environmental samples

A novel method based on pyrolysis-capillary gas chromatography-mass spectro metry (CGC-MS) was developed for the quantitative analysis of polyvinylchlo ride (PVC) in solid environmental samples like sludge and dust. The samples are extracted and the extract is fractionated by solid-phase extraction (S PE). Possibly interfering biological and frequently occuring synthetic poly mers are removed by this clean-up. The final extract is analyzed by pyrolys is-CGC-MS. Selective detection of PVC is performed by using specific marker s in the pyrogram, Quantitation is done on naphthalene. Good linearity was obtained in a range from 0.5 to 100 mug applied to the pyrolyser. The limit of quantitation (LOQ) in sludge and dust samples is 10 mg/kg dry mass. A c orrelation between PVC and phthalates was made for sewage sludge samples. ( C) 2001 Elsevier Science B.V. All rights reserved.