The emission spectra of Ne6+ and Ne7+ ions generated by beam-foil excitatio
n in the range 18-48 nm show a number of lines arising from doubly excited
levels. Hartree-Fock calculations using superpositions of quasi-degenerate
configurations provided many of the identifications, as did interpolations
along the lithium-like and beryllium-like isoelectronic sequences. From the
se observations, energies of Ne (VII) 1s2s2pnl and 1s2p(2)n'l' configuratio
ns are derived for the n = 3 and 4 levels. This has led to a revision of se
veral Ne v(II) levels previously reported in the literature. In addition, s
even new 3d-4f transitions were found between doubly excited states in lith
ium-like Ne v(III)**.