Citation
Na. Troitski et al., NMR study of 1-hydro-2,3,4,5-tetraphenylsilole derivatives, MAIN GR MET, 24(1), 2001, pp. 1-4
Citations number
24
Categorie Soggetti
Chemistry
Journal title
MAIN GROUP METAL CHEMISTRY
ISSN journal
07921241
→ ACNP
Volume
24
Issue
1
Year of publication
2001
Pages
1 - 4
Database
ISI
SICI code
0792-1241(2001)24:1<1:NSO1D>2.0.ZU;2-O
Abstract
The C-13 and H-1 NMR spectra of siloles C4Ph4SiRH (R = Cl, Ph, H, Me, t-Bu)
have been completely assigned using 2D NMR techniques. Values of the coupl
ing constants (1)J(SiX) (X = C, H) were measured. The analysis of the chemi
cal shifts delta (C-ipso) and (1)J(SiH) showed their linear dependence on T
aft's substituent constant.