The Edinburgh-Cape Blue Object Survey is an ongoing project to identify and
analyse a large sample of hot stars selected initially on the basis of pho
tographic colours (down to a magnitude limit B similar to 18.0) over the en
tire high-Galactic-latitude southern sky, and then studied with broad-band
UBV photometry and medium-resolution spectroscopy. Due to unavoidable error
s in the initial candidate selection, stars that are likely metal-deficient
dwarfs and giants of the halo and thick-disc populations are inadvertently
included, yet are of interest in their own right. In this paper we discuss
a total of 206 candidate metal-deficient dwarfs, subgiants, giants, and ho
rizontal-branch stars with photoelectric colours redder than (B - V)(o) = 0
.3, and with available spectroscopy. Radial velocities, accurate to similar
to 10-15 km s(-1), are presented for all of these stars. Spectroscopic met
allicity estimates for these stars are obtained using a recently recalibrat
ed relation between Ca II K-line strength and (B - V)(o) colour. The identi
fication of metal-poor stars from this colour-selection technique is remark
ably efficient, and competitive with previous survey methods. An additional
sample of 186 EC stars with photoelectric colours in the range -0.4 less t
han or equal to (B - V)(o) < 0.3, composed primarily of field horizontal-br
anch stars and other, higher gravity, A- and B-type stars, is also analysed
. Estimates of the physical parameters T-eff, log g, and [Fe/H] are obtaine
d for cooler members of this subsample, and a number of candidate RR Lyrae
variables are identified.