Capillary wave dynamics on glycerol surfaces has been investigated by means
of x-ray photon correlation spectroscopy performed at grazing angles. The
measurements show that thermally activated capillary wave motion is slowed
down exponentially when the sample is cooled below 273 K. This finding dire
ctly reflects the freezing of the surface waves. The wave-number dependence
of the measured time constants is in quantitative agreement with theoretic
al predictions for overdamped capillary waves.